Evaluation of the Residual Mass Fractionation in High-Precision Cr Isotopic Analysis with TIMS     

Tetsuya Yokoyama  Yusuke Ohkuma  Keiji Nishikawa  Koki Sumiya  Ikshu Gautam 《Geostandards and Geoanalytical Research》2023,47(2):415-435

The Cr isotope ratios of terrestrial and extra-terrestrial materials are emerging as one of the most important tracers in geosciences. Previous studies on Cr isotopic measurements using TIMS have found that there is residual Cr isotopic fractionation between the mass-fractionation-corrected ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios, which may cause an offset of obtained ratios from the reference values. The residual fractionation was thought to be caused by the evaporation of Cr-oxide species during thermal ionisation, but the mechanism by which this residual fractionation could be reduced remained unclear. Here we revisit the issue of residual fractionation and propose that this problem can be alleviated by utilising W filaments instead of conventionally used Re filaments for Cr ionisation. Using W filaments, the formation of CrO⁺ was suppressed during heating as the filament temperature was ~ 100 °C lower than when Re filaments were used. In repeated measurement of a carbonaceous chondrite, the intermediate precisions of ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios in the W filament runs were two to three times better than those of the Re filament runs. Therefore, the new finding of this study will be of key importance for future studies of Cr isotopes for terrestrial and extra-terrestrial materials.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114000917     

Miyuki Tahata  Yusuke Sawaki  Yuichiro Ueno  Manabu Nishizawa  Naohiro Yoshida  Toshikazu Ebisuzaki  Tsuyoshi Komiya  Shigenori Maruyama 《地学前缘(英文版)》2015,6(1):121-136

Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations.  相似文献   

Inverse analysis of an embankment on soft clay by extended Bayesian method     

Yusuke Honjo  Liu Wen-Tsung  Soumitra Guha 《国际地质力学数值与分析法杂志》1994,18(10):709-734

A new type of indirect inverse analysis procedure is proposed to overcome the difficulties the geotechnical inverse analyses are encountering (such as unstability and non-uniqueness of the solutions as well as multicollinearity). These difficulties are eased by combining the objective information (i.e. the observation data) and the subjective information (i.e. the prior information) in an appropriate manner by so-called extended Bayesian method. The method is based on a new view on Bayesian model proposed by Akaike. The problem of model identification in the inverse analysis is also tackled by applying well-known AIC but of the Bayesian version. A case study on an embankment on soft clay is presented to illustrate the effectiveness of the new method. A rather thorough review on the geotechnical inverse analysis is also presented to indicate the necessity of the proposed procedure. An appendix is attached to summarize the statistical background of the new method.  相似文献   

Parametric infinite element for seepage analysis     

Yusuke Honjo  Gyaneswor Pokharel 《国际地质力学数值与分析法杂志》1993,17(1):45-66

A set of mapping functions in the form of convergent series for an infinite element, which is capable to include the infinitely distanced constant head boundary condition from the area of disturbance (e.g. pumping), is proposed based on the asymptotic far-field behaviour of typical seepage flow problems. The derived mapping functions have been successfully used in three-dimensional point symmetric, two-dimensional axi-symmetric and one-dimensional unidirectional flow for the fixed head boundary at infinite distance. The result shows excellent agreement with analytical solution. For the first time, the mapping function of an infinite element is presented in the form of a convergent series. The infinite elements are really capable of reducing the cost and efficiency of conventional finite element analysis. Finally, a figure is also proposed to indicate the required size of the near field to obtain accurate drawdown at specified locations based on some calculations for two-dimensional radial flow case.  相似文献   

Detailed analysis for earthquake source spectrum represented by stochastic impulse train and its applications     

Hitoshi?MorikawaEmail author  Sumio?Sawada  Yusuke?Ono 《Journal of Seismology》2005,9(2):151-170

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Meltwater discharge during the Holocene from the Wilkes subglacial basin revealed by beryllium isotope analysis of marine sediments     

Bethany Behrens  Yosuke Miyairi  Adam D. Sproson  Masako Yamane  Yusuke Yokoyama 《第四纪科学杂志》2019,34(8):603-608

Understanding Antarctic Ice Sheet dynamics related to global climate change is of scientific and societal interest as the future behaviour of the ice sheet under the currently changing climate is unknown. We present beryllium‐10 (¹⁰Be) analysis of a high‐resolution marine sediment core from the Adélie Basin near the eastern Wilkes Land margin, which is susceptible to marine ice sheet instability due to the low‐lying nature and down‐sloping trough of the Wilkes Subglacial Basin. Combined with a newly constructed age model using compound specific radiocarbon dates, the data reveal three events associated with high meteoric ¹⁰Be at ca. ~10 ka, ca. ~6.5 ka and from ca. ~4 ka. We interpret these high meteoric ¹⁰Be events to be derived from the deposition of ¹⁰Be released from the ice sheet during meltwater discharge. In particular, the shift to higher meteoric ¹⁰Be concentration at~4 ka may correspond to changes in climate patterns at this time. Copyright © 2019 John Wiley & Sons, Ltd.  相似文献   

Bayesian and Neural Network Approaches to Estimate Deep Temperature Distribution for Assessing a Supercritical Geothermal System: Evaluation Using a Numerical Model     

Ishitsuka  Kazuya  Kobayashi  Yosuke  Watanabe  Norihiro  Yamaya  Yusuke  Bjarkason  Elvar  Suzuki  Anna  Mogi  Toru  Asanuma  Hiroshi  Kajiwara  Tatsuya  Sugimoto  Takeshi  Saito  Ryoichi 《Natural Resources Research》2021,30(5):3289-3314

The temperature distribution at depth is a key variable when assessing the potential of a supercritical geothermal resource as well as a conventional geothermal resource. Data-driven estimation by a machine-learning approach is a promising way to estimate temperature distributions at depth in geothermal fields. In this study, we developed two methodologies—one based on Bayesian estimation and the other on neural networks—to estimate temperature distributions in geothermal fields. These methodologies can be used to supplement existing temperature logs, by estimating temperature distributions in unexplored regions of the subsurface, based on electrical resistivity data, observed geological/mineralogical boundaries, and microseismic observations. We evaluated the accuracy and characteristics of these methodologies using a numerical model of the Kakkonda geothermal field, Japan, where a temperature above 500 °C was observed below a depth of about 3.7 km. When using geological and geophysical knowledge as prior information for the machine learning methods, the results demonstrate that the approaches can provide subsurface temperature estimates that are consistent with the temperature distribution given by the numerical model. Using a numerical model as a benchmark helps to understand the characteristics of the machine learning approaches and may help to identify ways of improving these methods.

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Anomalous change in atmospheric radon concentration sourced from broad crustal deformation: A case study of the 1995 Kobe earthquake     

Yumi Yasuoka  Yusuke Kawada  Yasutaka Omori  Hiroyuki Nagahama  Tetsuo Ishikawa  Shinji Tokonami  Masahiro Hosoda  Tetsuo Hashimoto  Masaki Shinogi 《Applied Geochemistry》2012

Before the Kobe earthquake, an anomalous increase in atmospheric Rn concentration was observed. By separating the measured concentration of atmospheric Rn into three components according to the distance from the monitoring station, the variation of Rn exhalation rate can be estimated for the respective area using the daily minimum and maximum concentrations. The mean rate of Rn exhalation gradually increased in an area of 20 km around the monitoring station, becoming five times higher than normal in the period between October 1994 and the date of the earthquake. This area had a large co-seismic displacement of up to 30 cm, which roughly corresponds to the crustal strain of 10⁻⁶-order, and it is considered the main source for the atmospheric Rn prior to the Kobe earthquake. Analyses revealed that the pre-seismic change in the atmospheric Rn concentration exhibited an anomalous pattern which would yield information on the spatial distribution of the mechanical response of the ground.  相似文献   

Microfacies and diagenesis of older Pleistocene (pre‐last glacial maximum) reef deposits,Great Barrier Reef,Australia (IODP Expedition 325): A quantitative approach     

Eberhard Gischler  Alex L. Thomas  André W. Droxler  Jody M. Webster  Yusuke Yokoyama  Bernd R. Schöne 《Sedimentology》2013,60(6):1432-1466

During Integrated Ocean Drilling Program Expedition 325, 34 holes were drilled along five transects in front of the Great Barrier Reef of Australia, penetrating some 700 m of late Pleistocene reef deposits (post‐glacial; largely 20 to 10 kyr bp ) in water depths of 42 to 127 m. In seven holes, drilled in water depths of 42 to 92 m on three transects, older Pleistocene (older than last glacial maximum, >20 kyr bp ) reef deposits were recovered from lower core sections. In this study, facies, diagenetic features, mineralogy and stable isotope geochemistry of 100 samples from six of the latter holes were investigated and quantified. Lithologies are dominated by grain‐supported textures, and were to a large part deposited in high‐energy, reef or reef slope environments. Quantitative analyses allow 11 microfacies to be defined, including mixed skeletal packstone and grainstone, mudstone‐wackestone, coral packstone, coral grainstone, coralline algal grainstone, coral‐algal packstone, coralline algal packstone, Halimeda grainstone, microbialite and caliche. Microbialites, that are common in cavities of younger, post‐glacial deposits, are rare in pre‐last glacial maximum core sections, possibly due to a lack of open framework suitable for colonization by microbes. In pre‐last glacial maximum deposits of holes M0032A and M0033A (>20 kyr bp ), marine diagenetic features are dominant; samples consist largely of aragonite and high‐magnesium calcite. Holes M0042A and M0057A, which contain the oldest rocks (>169 kyr bp ), are characterized by meteoric diagenesis and samples mostly consist of low‐magnesium calcite. Holes M0042A, M0055A and M0056A (>30 kyr bp ), and a horizon in the upper part of hole M0057A, contain both marine and meteoric diagenetic features. However, only one change from marine to meteoric pore water is recorded in contrast with the changes in diagenetic environment that might be inferred from the sea‐level history. Values of stable isotopes of oxygen and carbon are consistent with these findings. Samples from holes M0032A and M0033A reflect largely positive values (δ¹⁸O: ?1 to +1‰ and δ¹³C: +1 to +4‰), whereas those from holes M0042A and M0057A are negative (δ¹⁸O: ?4 to +2‰ and δ¹³C: ?8 to +2‰). Holes M0055A and M0056A provide intermediate values, with slightly positive δ¹³C, and negative δ¹⁸O values. The type and intensity of meteroric diagenesis appears to have been controlled both by age and depth, i.e. the time available for diagenetic alteration, and reflects the relation between reef deposition and sea‐level change.  相似文献   

Carbon and oxygen isotope chemostratigraphies of the Yangtze platform,South China: Decoding temperature and environmental changes through the Ediacaran     

Miyuki Tahata  Yuichiro Ueno  Tomoko Ishikawa  Yusuke Sawaki  Kazuki Murakami  Jian Han  Degan Shu  Yong Li  Junfeng Guo  Naohiro Yoshida  Tsuyoshi Komiya 《Gondwana Research》2013,23(1):333-353

Multicellular animals first appeared on the earth during the Ediacaran period. However, the relationship between the abrupt biological evolution and environmental changes is still ambiguous. In order to examine seawater temperature and the carbon cycle through the Ediacaran, we analyzed the carbon and oxygen isotope compositions of carbonate rocks from drill cores from the Three Gorges area, South China. Importantly, the core samples include the Nantuo tillite, corresponding to the Marinoan glaciation, through the Doushantuo to the lower Dengying Fms. in ascending order.The δ¹³C profile displays five positive and five negative anomalies (PI-1 to 5 and NI-1 to 5), and the oxygen isotopes display very high absolute values around 0‰ with the highest at + 1.83‰. The combined δ¹⁸O and δ¹³C chemostratigraphies display both positive and negative correlations between the δ¹⁸O and δ¹³C values. The occurrence of the negative correlations supports the preservation of primary δ¹⁸O and δ¹³C values.The sample NI-4 has a negative correlation of the δ¹⁸O and δ¹³C excursions. The correlation supports a primary signature for both δ¹⁸O and δ¹³C variations. The positive δ¹⁸O excursion, accompanied by evidence of a eustatic sea-level fall, provides direct evidence for global cooling in the mid-Ediacaran; the 580 Ma Gaskiers Glaciation is a potential candidate for this global cooling event. The negative δ¹³C excursion was possibly caused by an increase in remineralization of dissolved organic carbon (DOC) due to enhanced continental weathering during the glaciation.Sample NI-5 is characterized by very low δ¹³C values, down to ? 10‰, corresponding to the Shuram-Wonoka-Pertatataka Excursion. The cause of the δ¹³C negative excursion is still not clear. However, a ubiquitous occurrence in excursions worldwide, and the lower δ¹³C values in deeper sections favor the enhancement of remineralization and respiration rather than secondary alteration, a restricted sea environment and lithification in coastal areas.  相似文献